catalytic synthesis n-alkyl-3-acetyl-2-methylpyrroles using zno nanostructure

Authors

a.s. shahvelayati

m. sabbaghan

s. banihashem

abstract

a simple, green synthesis of n-alkyl-3-acetyl-2-methylpyrrole derivatives using zno nanoparticles from the three component reaction of aliphatic amines, acetylacetone (as a 1,3-dicarbonyl compound) and α-haloketones under solvent-free condition is described.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Catalytic Synthesis N-alkyl-3-acetyl-2-methylpyrroles using ZnO Nanostructure

A simple, green synthesis of N-alkyl-3-acetyl-2-methylpyrrole derivatives using ZnO nanoparticles from the three component reaction of aliphatic amines, acetylacetone (as a 1,3-dicarbonyl compound) and α-haloketones under solvent-free condition is described.

full text

Catalytic Synthesis N-alkyl-3-acetyl-2-methylpyrroles using ZnO Nanostructure

A simple, green synthesis of N-alkyl-3-acetyl-2-methylpyrrole derivatives using ZnO nanoparticles from the three component reaction of aliphatic amines, acetylacetone (as a 1,3-dicarbonyl compound) and α-haloketones under solvent-free condition is described.

full text

A new synthesis of N-alkyl 3-acetyl-4-methoxycarbonylmethyl-2-methyl-1,4-dihydropyridines utilizing sec-aminodienyl esters with acetylacetone.

The reactions of sec-aminodienyl esters 3 with acetylacetone (4) afforded N-alkyl 3-acetyl-4-methoxycarbonylmethyl-2-methyl-1,4-dihydropyridines 5 and enamines 6, providing a new azaelectrocyclization reaction.

full text

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis.

n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when ((tBu)PCP)IrH2 was paired with tungsten monoaryloxide pyrrolide complexes such as W(NAr)(C3H6)(pyr)(OHIPT) (1a) [Ar = 2,6-i-Pr2C6H3; pyr = pyrrolide; OHIPT = 2,6-(2,4,6-i-Pr3C6H2)2C6H3O]. Complex 1a was also esp...

full text

Isoquinoline Promoted Synthesis of alkyl 2-(1-alkyl-5-oxo-3-phenyl-2-thioxotetrahydro-4H-imidazol-4-yliden) acetate derivatives

Derivatives of thiazolidinone ring systems are known to act as anti-HIV infections , analgesic, anti-bacterial, anti-convulsant, anti parasitic, potential anti-inflammatory and herbicidal agents. Due biological activities of thiazolidinones ring, several methods for their synthesis have been illustrated in literature. Imidazolidine-2-thiones were synthesized by the oxidative cyclization of 1-be...

full text

Synthesis of N-alkyl isatins via oxidative cyclization of N-alkyl 2-bromo(chloro)acetanilides.

A highly efficient method for the synthesis of N-alkyl isatins starting from N-alkyl 2-bromo or 2-chloro acetanilides is described. The starting materials are easy to prepare and the yields of isatins are generally high. Operationally the reaction is very simple to run. Even though best results were obtained with a catalytic amount of CuI, the reactions of N-alkyl 2-bromo acetanilides actually ...

full text

My Resources

Save resource for easier access later


Journal title:
international journal of bio-inorganic hybrid nanomaterials

Publisher: islamic azad university - varamin branch

ISSN 2251-8533

volume 4

issue 2 2015

Keywords
[ ' n ' , ' a l k y l ' , 3 , ' a c e t y l ' , 2 , ' m e t h y l p y r r o l e s ' , ' z n o n a n o p a r t i c l e s ' , ' t h r e e c o m p o n e n t r e a c t i o n s ' , ' s o l v e n t ' , ' f r e e r e a c t i o n s ' , ' a c e t y l a c e t o n e ' ]

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023